Chemistry 111 Test Questions – Flashcards

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Atom & composition
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-basic unit of an element that can enter into a chemical combination
-composed of protons, neutrons, and electrons
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Protons(charge and mass)
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- (+) or +1
- m=1837 times that of an electron
- actual mass= 1.673 x10^(-24)
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Electron(charge and mass)
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-(-) or -1
- mass=9.110x10^(-28)
- mass=1/1837 of a H atom
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Ions (names of (+/-))
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- cations- (+) - loses electrons
-anions- (-) - gains electrons
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Atomic number is the number of..
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- number of protons
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Mass number is the number of..
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- protons and neutrons
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Isotopes
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- atoms with the same number of protons/atomic# but has different mass numbers
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Atomic weight
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- average mass of all naturally occuring isotopes of that element
- takes into account relative abundance of the elements isotopes
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Percent abundance
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- % of atoms of a natural sample of the pure element represented by a particular isotope to describe isotope composition for an element
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Periodic Table (horiz/vert)
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- Horizontal- period
- Vertical- group
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Group 1A
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- alkali metals
- very reactive
-shiny solids that react vigorously with air, water,
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Group 2A
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- alkaline earth metals
- not quite as reactive
- react with water to form alkaline solutions
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Group 6A
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- chalogens
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Group 7A
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- halogens
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Group 8A
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- noble gases
- rare gases/ inert gases
- least reactive elements
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Representative elements
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- main group elements
- group number followed by letter A
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Transition metals
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- Group # followed by letter B
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Lanthanides and Actinides
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- portions of periods 6 and 7 that are below the main body
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Metal properties
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- good conductors of heat and electricity
-high luster (shiny)
- high melting point
- high density
- solids at room temperature (Hg- mercury- liquid)
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Nonmetal properties
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-poor conductors of heat and electricity
- no lustrous, relative dull
- low melting point and density
- C, P, S, SE, I are solids
-Br- liquid
- the rest are gases H, N, O, F, Cl, He, Ar, Kr, Xe, Ra
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Metalloids or semimetals
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- intermediate between properties of metal and nonmetals
- raw materials or semiconductors device that make the electronic industry possible
- B, Si, Ge, Te, Sb, As, Po
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Molecules
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- aggregate of at least 2 atoms in a definite arrangement held together by chemical forces/ chemical bonds
-smallest unit of a compound
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Diatomic molecule
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- 2 atoms
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Allotropes
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- one or two or more distinct forms of an element
- differ in chemical and physical propterties
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Covalent (molecular) compound
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- all elements in the compund are nonmetals
- contain discrete molecular units
- inorganic acids
-many are binary compounds (02)
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Molecular covalent compound
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-molecule formed by covalent bonds in which atoms share one or more pairs of valence electrons
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Network Covalent Compound
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- chemical compound in which atoms are bonded by covalent bonds in a continuous network (SiO2)
- there are no individual molecules and the entire crystal may be considered a macromolecule
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Molecular vs Empirical formula
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-Molecular- shows the exact # of atoms of each element in the smallest unit of a substance
-Empirical- shows the simplest whole number ratio of the atoms in a substance molecule
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Structural Forumula
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-shows linkage of all the atoms in the molecule
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Condensed structural forumla
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-lists atoms present in groups to indicate connectivity between the atoms
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Molecular Compound naming
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- cation first, then anion
-first element listed is the one "more metal like"
-prefixes are written before the name of the element to indicate # of atoms present
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Mono, Di, Tri, deca, tetra, penta, hexa, hepta, octa, nona, deca, dodeca
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1,2,3,4,5,6,7,8,9
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Molecular compound exceptions-NH3
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-Ammonia
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Molecular compound exceptions-CH4
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-methane
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Molecular compound exceptions-H20
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-water
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Molecular compound exceptions-PH3
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-phosphine
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Molecular compound exceptions-H2S
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-hydrogen sulfide
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Molecular compound exceptions-B2H6
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- diborane
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Hydrocarbon
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-carbon and hydrogen compounds
-simplest of all organic compounds
-used as fuels starting material for chemistry industry
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How are organic compounds determined
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-by functional groups chemically bound to parents compound
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Functional group -OH
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-hydroxyl group
-alcohol
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Functional group -NH2
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- amino group
-amine
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Functional group -COOH
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-carbonxyl group
-carboxylic acid- organic acid
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Organic chemistry
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-the branch of chemistry that deals with carbon compound and functional groups
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Alkanes
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-have no branches
-*SINGLE* carbon chain/bond
-formula: CnH2n+2 where n is greater or equal to 1
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Alkenes
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-contains *at least one* carbon-carbon *double bond*
-formula: CnH2n where n is greater or equal to 1
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Alkynes
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-contain at *least one* carbon-carbon *triple bond*
-formula: CnH2n-2 where n is greater or equal to 1
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Acid
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-produces H+ ions in water
- any substance that dissolves and dissociated into ions and one is H+
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Naming acids
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- H cation called hydro-
- anion with the -ide ending becomes -ic
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Rules to writing acids
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-write the prefix hydro-
- followed by the stem of the 2nd element of the suffix add ic
-add the word acid
-make sure to add aqueous (aq) after the word "acid"
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Oxoacids
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- acids where anion is polyatomic
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How to name Oxoacids
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-if the ending is -ite -> change to -ous
if the ending is -ate -> change to -ic
- if there are more than 2 ions in the series, prefixes "hypo" (less than) and "per" (more than) are used
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NO3- (name and oxoacidic name & formula if applicable)
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-Nitrate
-HNO3 nitric acid
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oxoanions
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- polyatomic ions containing oxygen
- contain different numbers of oxygen
-are named by the number of oxygen in the ion
-if there are 2 in series, the one with more oxygen atoms ends in -ate
-the one with few ends with -ite
-more than 2 ions in the series, "hypo" and "per" are used
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Ionic Compounds
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-formed from cations and anions
-species that carry a net (+) or(-) charge
-most are solids with a high melting point
-
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Monatomic ion
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-single atom ion
-EX:K+, O-2, Al3+
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Polyatomic ion
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- two or more ions
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Polyatomic ion: SO42-
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-sulfate
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Polyatomic ion:No3-
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-nitrate
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Polyatomic ion: NH4+
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-Ammonium
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Polyatomic ion: OH-
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-hydroxide
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Elements in the same group have...
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-similar chemical and physical properties
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A groups
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-are the main-group elements
-also called the representative elements
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B groups
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-are transition metals
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Crisscross rule
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-the subscript on the cation is numerically equal to the charge of the anion and the subscript of the anion is numerically equal to the charge of the cation
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Polyatomic ions
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-groups of covalently bonded ions
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Carbonate Formula
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CO32-
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Hydrocarbonate or bicarbonate Formula
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HCO3-
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Nitrate Formula
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NO3-
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Permaganate Formula
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KMnO4
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Phosphate Formula
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PO43-
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Ionic compund rules and properties
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-formula written in the empirical
-they are 3-D crystal networks
-formula tells cations to anions
-charges in ionic compounds MUST equal 0
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Chemical forumlas
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- express the composition of molecules and ionic compounds in terms of chemical symbols
-indicates number of elements and relative number of atoms in a compound
-change the number in a subscript and you change the compound
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Ionic Compound naming rules
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-write the name of the cation
-write the name of the stem for the anion and add the suffix "-ide"
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Name the polyatomic ion: KNO3
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-KNO3= potassium nitrate
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Name the polyatomic ion: Fe(OH)2
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- iron(II) hydroxide
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Name the polyatomic ion: KNO2
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- Potassium nitrite
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Inorganic compounds
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- formed from more than 3 elements
-one or more of the ions is polyatomic
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Only metal liquid at RT
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-mercury (Hg)
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Only liquid nonmetal at RT
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-bromine Br
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11 gases at RT
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-hydrogen, nitrogen, oxygen, fluorine, chlorine, helium, neon, argon, krypton, xenon, and
radon
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Naming Inorganic Compounds
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-identify the ions
-name the cations in order given and follow with the names of the anions
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NaHCO3
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Sodium Hydrogen carbonate
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NaHSO4
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Sodium hydrogen sulfate
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Transition metals
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-uses the stock
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Stock system
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- for transition metals
-when a compound contains a metal that forms more than one cation, the charge on the cation or the metal is designated by a roman numeral immediately following the name of the metal
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Transition metals naming rules
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-Write the name of the cation
-write the charge of the cation as roman numerals in (...)
- write the stem of the anion and add "-ide"
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Copper(II) oxide
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-CuO
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Iron(III) chloride
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FeCl3
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Chromium(VI) sulfide
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CrS3
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Classical nomenclature
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-when a metaalic ion has only 2 types of cations, the name of the metal is modified with suffixes -ous (for the lower charge) and "-ic" (for the higher charge)
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Covalent
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-contain only nonmetals
-are named using prefixes to indicate # of each element in the formula
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Ionic
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-contain monatomic and polyatomic ions
-usually contain metals and nonmetals
-NEVER named using prefixes
-sometimes name with cation charge in roman numerals
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n
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Wedge-and-dash Model
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-is a two-dimensional representation of a three-dimensional
structure that can easily be drawn on paper
- bonds are represented by lines (bonds that lie in the plane of the paper)
-wedges (bonds that lie in front of the plane of the paper)
-dashes (bonds that lie behind the plane of the paper)
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Ball and-stick Model
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-shows atoms as colored spheres connected by sticks that represent
covalent bonds.
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Space-filling model
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-interpenetrating spheres represent the relative amount of
space occupied by each atom in the molecule
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Most common covalent bond categories
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-binary nonmetals and inorganic acids
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Binary nonmetal compounds
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-consist of only two elements, both nonmetals
- named using prefixes and -ide
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Hydrogen peroxide
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-H2O2
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Hydrazine
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-N2H4
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Nitric oxide
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NO
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Inorganic acids
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-form H+ ions when dissolved in water
-compounds that contain hyderogen and one or more nonmetals
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Inorganic acids are named...
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-like binary compounds but without prefixes
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hydrogen halides are named... gas phase...aqueous phase....
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-like binary compounds *when in gas form*
- are named with common names when aqueous
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Metals in Groups 1A, 2A, and 3A form.... ions and there charge is
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-equal to the group number of the element.
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Nonmetals in Groups 5A, 6A, and 7A form....ions and there charge is
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-equal to 8 minus the group number of the element.
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CN2-
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-Cyanide
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CH3CO2-
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-Acetate
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S2O3^2-
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-Thiosulfate
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