Organic Reactions

Ways to make alcohols

1. BH3

H2O2/aq NaOH

Syn/AM

 

2.  Hg(OAc)2 /THF/ H2O

NaBH4

 –/Mark

 

3.  H+ /H2O or aq. H2O4

–/Mark 

 

Difference between reaction of HBr/ peroxides and HBr to d.bond

Peroxide – Br to the least sub. side of d.bond to make stable radical

 

Dark – H to the most sub. side to make stable carbocation. 

Br2/H2O or XOH
Halohydrin – anti/Mark

X2 in CH2Cl2

 

Disubed halogen. Anti/–
x

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